Beilstein J. Org. Chem.2015,11, 2671–2676, doi:10.3762/bjoc.11.287
derivatisation and facilitate the incorporation of the facially polarised all-cis-1,2,4,5-tetrafluorocyclohexane motif into more advanced molecular scaffolds.
Keywords: cyclohexanecarbonylation; fluorine containing building blocks: organofluorine chemistry; Introduction
Selectively fluorinated building blocks
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Graphical Abstract
Figure 1:
All cis-hexafluoro- 1 and tetrafluorocyclohexanes 2 and 3 result in facially polarised ring motifs ...